HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl Acetate → HCID 5171266, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl Acetate | HCID 8857 | — |
| Reactant | 1-(Chloromethyl)-1H-benzotriazole | HCID 3328222 | — |
| Reactant | Phthalimide potassium salt | HCID 24194345 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 5171266 | HCID 5171266 | — |
Reaction Steps
A solution of potassium phthalimide (5.55 g) and crude 1-(chloromethyl)benzotriazole (5.02 g) in 75 ml dimethylformamide was stirred at ambient temperature for 2 hours. An additional portion of potassium phthalimide (1.0 g) was added. After 2 hours an aqueous ethyl acetate extractive work up gave a crude solid. Recrystallization from acetonitrile gave a colorless solid, m.p. 177°-180° C. (5.49 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04350752 |
| Source dataset | uspto-grants-1982_09 |
| ORD ID | ord-4d3a528699ec406d9152dc77f524711c |
| Source note | uspto-grants-1982_09 |