HuagongsheHuagongshe Chemistry Print Report · For research reference only
Toluene → HCID 54150769, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Toluene | HCID 1140 | — |
| Reactant | Sodium 2-methylbutan-2-olate | HCID 2733478 | — |
| Reactant | 2-[3-(Benzenesulfonyl)propyl]cyclododecan-1-one | HCID 20501203 | — |
| Solvent | Dimethyl Sulfoxide | HCID 679 | — |
| Product | HCID 54150769 | HCID 54150769 | 76% |
Reaction Steps
18.2 g (0.05 mole) of 2-(3-phenylsulfonyl-prop-1-yl)-cyclododecanone, 33.0 g (0.30 mole) of sodium tert-pentoxide and 100 ml of toluene were subjected to the treatments described sub letter (a). After addition of 15 ml of DMSO, heating at 110° for 4 hours and final treatments as indicated hereinabove, there were isolated 7.75 g (76% yield) of the desired compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04351977 |
| Source dataset | uspto-grants-1982_09 |
| ORD ID | ord-187c8e37fd624e2c8bb4f4eef0b70112 |
| Source note | uspto-grants-1982_09 |