HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 22761653, compound → HCID 22761654, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 22761653 | HCID 22761653 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Rhodium | HCID 23948 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | HCID 22761654 | HCID 22761654 | — |
Reaction Steps
The solution of 300 mg of N-(2-acetoxymethyl-4-nitrophenyl)-4-chlorophthalimide in 35 ml of ethyl acetate is hydrogenated with 200 mg of 5% rhodium on carbon at 2.5 atmospheres of hydrogen pressure for 3 hours. After filtration from the catalyst, the residue is crystallized from ethyl acetate-hexane to give the N-(2-acetoxymethyl-4-aminophenyl)-4-chlorophthalimide melting at 136°-138°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04124593 |
| Source dataset | uspto-grants-1978_11 |
| ORD ID | ord-4bbb3df379ec45fc819b84726307fe71 |
| Source note | uspto-grants-1978_11 |