HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methane → Butanal, 4-(acetyloxy)-2-methylene-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methane | HCID 297 | — |
| Reactant | 2-Butene-1,4-diol diacetate | HCID 140402 | — |
| Catalyst | Rhodium | HCID 23948 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | Butanal, 4-(acetyloxy)-2-methylene- | HCID 11083989 | 54% |
Reaction Steps
The procedure of Example 7 was repeated using 1,4-diacetoxy-2-butene (170 g.) and 5% by weight rhodium on 95% by weight charcoal (1.12 g.) in benzene (340 g.). The reaction took 6 hours to go to completion. Work-up in the manner of Example 7 gave a 54% yield of 2-formyl-4-acetoxybutene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04124619 |
| Source dataset | uspto-grants-1978_11 |
| ORD ID | ord-b3e7fe979de14ed89e8e6ef60d30d599 |
| Source note | uspto-grants-1978_11 |