HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Naphthalenesulfonic acid → methoxy-N-(2-methoxy-1-methylethyl)-3,4-Xylidine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Naphthalenesulfonic acid | HCID 8420 | — |
| Reactant | Methoxyacetone | HCID 22172 | — |
| Reactant | Methyl 2-methyl-5-nitrobenzyl ether | HCID 12767666 | — |
| Catalyst | Platinum | HCID 23939 | — |
| Product | methoxy-N-(2-methoxy-1-methylethyl)-3,4-Xylidine | HCID 20563862 | — |
Reaction Steps
A mixture of methyl 2-methyl-5-nitrobenzyl ether (12 g, 0.066M), methoxyacetone [20 g (used as solvent)], 2-naphthalenesulfonic acid (0.3 g) and 5% Pt/C (0.7 g) is shaken on a Parr hydrogenator maintaining the temperature below 40° with external cooling. The theoretical amount of hydrogen (0.26M) is consumed and further uptake ceases after 2 hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04124639 |
| Source dataset | uspto-grants-1978_11 |
| ORD ID | ord-7e854d4f22c9421fbe43520b06696dff |
| Source note | uspto-grants-1978_11 |