m-Toluidine → HCID 12767769, compound

HRID 1703532Notes

Reaction equation

HRID 1703532 reaction equation
NC1C=CC=C(C)C=1.[CH2:9]([C:11]1[CH:22]=[C:21]([N+:23]([O-:25])=[O:24])[C:14]([NH:15][CH:16]([CH2:19][CH3:20])[CH2:17][CH3:18])=[C:13]([N+:26]([O-:28])=[O:27])[C:12]=1[CH2:29]OC)[CH3:10]>>[CH2:9]([C:11]1[CH:22]=[C:21]([N+:23]([O-:25])=[O:24])[C:14]([NH:15][CH:16]([CH2:17][CH3:18])[CH2:19][CH3:20])=[C:13]([N+:26]([O-:28])=[O:27])[C:12]=1[CH3:29])[CH3:10]

Participants

3

Reactant 2

HCID 7934m-ToluidineHCID 12767745HCID 12767745, compound

Product 1

HCID 12767769HCID 12767769, compound

Procedure

The preceding m-toluidine was dinitrated in a manner similar to that used for 4-ethyl-N-(1-ethylpropyl)-α-methoxy-2,6-dinitro-m-toluidine to give the product after purification by chromatography with m.p. 51°-53°.

Workup

  1. customto give the product
  2. customafter purification by chromatography with m.p. 51°-53°

Sources & evidence

ORD record
ord-850a087442ec4460a483e44f6649b280
Source dataset
uspto-grants-1978_11
Patent number
US04124639

Reaction notes

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