Benzenamine, 2,6-dinitro-3-methyl- (9CI) → HCID 20563816, compound

HRID 1703533Notes

Reaction equation

HRID 1703533 reaction equation
[N+](C1C(C)=CC=C([N+]([O-])=O)C=1N)([O-])=O.[CH2:15]([C:17]1[CH:23]=[C:22]([N+:24]([O-:26])=[O:25])[C:20]([NH2:21])=[C:19]([N+:27]([O-:29])=[O:28])[C:18]=1[CH2:30]OC)[CH3:16]>>[CH2:15]([C:17]1[CH:23]=[C:22]([N+:24]([O-:26])=[O:25])[C:20]([NH2:21])=[C:19]([N+:27]([O-:29])=[O:28])[C:18]=1[CH3:30])[CH3:16]

Participants

3

Reactant 2

HCID 51035Benzenamine, 2,6-dinitro-3-methyl- (9CI)HCID 12767746HCID 12767746, compound

Product 1

HCID 20563816HCID 20563816, compound

Procedure

The above 2,6-dinitro-m-toluidine was dealkylated in a manner similar to that described for the preparation of 4-ethyl-α-methoxy-2,6-dinitro-m-toluidine. The desired product after recrystallization from hexane had m.p. 101°-101.5° C.

Workup

  1. customThe desired product after recrystallization from hexane

Sources & evidence

ORD record
ord-6d91a363b2b24f4a9fd2a0091f6104ec
Source dataset
uspto-grants-1978_11
Patent number
US04124639

Reaction notes

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