Ethylamine → HCID 54553238, compound

HRID 1703577Notes

Reaction equation

HRID 1703577 reaction equation
Cl[CH2:2][CH2:3][O:4][C:5](=[C:12]1[CH:17]2[CH2:18][CH:14]3[CH:15]([CH2:16]2)[CH:13]13)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.[CH2:19]([NH2:21])[CH3:20]>C1C=CC=CC=1>[CH2:19]([NH:21][CH2:2][CH2:3][O:4][C:5](=[C:12]1[CH:17]2[CH2:18][CH:14]3[CH:15]([CH2:16]2)[CH:13]13)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH3:20]

Participants

4

Reactant 2

HCID 6341EthylamineHCID 53965375HCID 53965375, compound

Product 1

HCID 54553238HCID 54553238, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

A solution of 90 g. (0.345 mol) of β-chloroethyl-{α[tricyclo-(2.2.1.02.6)hept-3-ylidene]-benzyl}-ether and 69 g. (1.53 mol) of ethylamine in 250 ml. of anhydrous benzene was heated for 5 hours to 140° C. in a 1 litre capacity autoclave. After cooling, the ethylamine hydrochloride was filtered off under suction, the mother liquor concentrated in vacuo and the residue subjected to acid-alkaline working up. The basic fraction was fractionated in vacuo.

Workup

  1. temperatureAfter cooling
  2. filtrationthe ethylamine hydrochloride was filtered off under suction
  3. concentrationthe mother liquor concentrated in vacuo

Sources & evidence

ORD record
ord-9c743158058e40108ac20cc83d2f5d6d
Source dataset
uspto-grants-1978_11
Patent number
US04124716

Reaction notes

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