Water → HCID 22760978, compound

HRID 1703973Notes

Reaction equation

HRID 1703973 reaction equation
[O:1]=[C:2]1[CH2:20][CH2:19][C:5]2[C:6]3[CH:18]=[CH:17][CH:16]=[CH:15][C:7]=3[O:8][C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=3[C:4]=2[CH2:3]1.[H-].[Al+3].[Li+].[H-].[H-].[H-].O>CCOCC>[OH:1][CH:2]1[CH2:20][CH2:19][C:5]2[C:6]3[CH:18]=[CH:17][CH:16]=[CH:15][C:7]=3[O:8][C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=3[C:4]=2[CH2:3]1

Participants

5

Reactant 3

HCID 962WaterHCID 21226445Aluminium lithium hydrideHCID 22760937HCID 22760937, compound

Product 1

HCID 22760978HCID 22760978, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

6.2 g of 2-keto-1,2,3,4-tetrahydro-tribenzo(b,d,f)-oxepine are added to a suspension of 3.7 g of lithiumaluminiumhydride in 300 ml of dry ether. After refluxing for 2 hours 14.8 ml of water are added carefully. The suspension obtained is filtered off and after that the filtrate is dried and evaporated to dryness.

Workup

  1. additionare added carefully
  2. customThe suspension obtained
  3. filtrationis filtered off
  4. customafter that the filtrate is dried
  5. customevaporated to dryness

Sources & evidence

ORD record
ord-68cde95075704ef5a6e83ded9e89eba2
Source dataset
uspto-grants-1978_11
Patent number
US04125718

Reaction notes

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