4-Phenoxyphenol → HCID 54217073, compound

HRID 1704144Notes

Reaction equation

HRID 1704144 reaction equation
[O:1]([C:8]1[CH:13]=[CH:12][C:11]([OH:14])=[CH:10][CH:9]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Br[CH:16]([C:21]1[CH:26]=[CH:25][C:24]([O:27][CH2:28][CH:29]([O:31][C:32]2[CH:37]=[CH:36][C:35]([F:38])=[CH:34][CH:33]=2)[CH3:30])=[CH:23][CH:22]=1)[C:17]([O:19][CH3:20])=[O:18]>>[O:1]([C:8]1[CH:9]=[CH:10][C:11]([O:14][CH:16]([C:21]2[CH:22]=[CH:23][C:24]([O:27][CH2:28][CH:29]([O:31][C:32]3[CH:37]=[CH:36][C:35]([F:38])=[CH:34][CH:33]=3)[CH3:30])=[CH:25][CH:26]=2)[C:17]([O:19][CH3:20])=[O:18])=[CH:12][CH:13]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 132544-PhenoxyphenolHCID 54386710HCID 54386710, compound

Product 1

HCID 54217073HCID 54217073, compound

Procedure

As described in Example 35, 4.66 g of p-phenoxyphenol is reacted with methyl bromo{p-[2-(p-fluorophenoxy)propoxy]phenyl}acetate (0.02 mole) in refluxing methanol-benzene for 24 hrs to give the product as a viscous oil.

Sources & evidence

ORD record
ord-721cb78afd1048b3beed47edbef56e2f
Source dataset
uspto-grants-1978_11
Patent number
US04125732

Reaction notes

Loading…