HCID 514300, compound → HCID 70625137, compound

HRID 1704177Notes

Reaction equation

HRID 1704177 reaction equation
[CH2:1]([C:3](=[CH:12][CH2:13][CH2:14][C:15]1[CH:20]=[CH:19][C:18]2[O:21][CH2:22][O:23][C:17]=2[CH:16]=1)[CH2:4][CH2:5][CH:6]1[CH2:10][CH2:9][CH2:8][C:7]1=[O:11])[CH3:2].[CH2:24]([Mg]Br)[CH3:25]>>[CH2:24]([C:7]1([OH:11])[CH2:8][CH2:9][CH2:10][CH:6]1[CH2:5][CH2:4][C:3]([CH2:1][CH3:2])=[CH:12][CH2:13][CH2:14][C:15]1[CH:20]=[CH:19][C:18]2[O:21][CH2:22][O:23][C:17]=2[CH:16]=1)[CH3:25]

Participants

3

Reactant 2

HCID 514300HCID 514300, compoundHCID 178418443HCID 178418443, compound

Product 1

HCID 70625137HCID 70625137, compound

Procedure

2-[3-Ethyl-6-(3,4-methylenedioxyphenyl)-3-hexenyl]cyclopentanone can be treated with ethylmagnesium bromide according to the procedure of Example 2, part (c) to give 1-ethyl-2-[3-ethyl-6-(3,4-methylenedioxyphenyl)-3-hexenyl]cyclopentanol [XV; Ar is 3,4-methylenedioxyphenyl, Y is C(C2H5)=CHCH2CH2, R' is C2H5, m is 1].

Sources & evidence

ORD record
ord-df3eb2fd5bce4c5f8f28dc300242d928
Source dataset
uspto-grants-1978_11
Patent number
US04125714

Reaction notes

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