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HRID1704199

反应详情

EQUATION

反应方程式

HRID 1704199 的结构方程式

REACTANTS

反应物

3
结构：O
HCID962

Water

H2O

结构：[C-]#N.[Na+]
HCID8929

Sodium cyanide (Na(CN))

CNNa

结构：CCN(CC)c1ccc(N=Nc2c(Cl)cc([N+](=O)[O-])cc2[N+](=O)[O-])c(NC(C)=O)c1
HCID3017688

N-(2-((2-Chloro-4,6-dinitrophenyl)diazenyl)-5-(diethylamino)phenyl)acetamide

C18H19ClN6O5

PRODUCTS

生成物

1
结构：CCN(CC)c1ccc(N=Nc2c(C#N)cc([N+](=O)[O-])cc2[N+](=O)[O-])c(NC(C)=O)c1
HCID90383

N-(2-((2-Cyano-4,6-dinitrophenyl)azo)-5-(diethylamino)phenyl)acetamide

C19H19N7O5

收率 82.5%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：N#CCCSCCC#N
溶剂HCID8151

3,3'-Thiodipropionitrile

C6H8N2S

CONDITIONS

反应条件

温度
132.5 °C

PROCEDURE

实验过程

7.175 parts of cuprous bromide are dissolved in 350 parts of bis-(β-cyanoethyl) sulfide. 43.45 parts of 3-acetamido-4-(2'-chloro-4',6'-dinitrophenylazo)-N,N-diethylaniline are introduced, and the mass is brought to 130° C. During 1 hour 30 minutes, in an open reactor, a solution of 6.35 parts of sodium cyanide in 20 parts of water is added to the mixture and the mixture is stirred for 4 hours at 130-135° C. The product formed is separated as in Example 1; 35.12 parts of 3-acetamido-4-(2'-cyano-4', 6'-dinitrophenylazo)-N,N-diethylaniline are obtained. The yield is 82.5%.

WORKUP

后处理

  1. customis brought to 130° C
  2. customThe product formed
  3. customis separated as in Example 1