HRID1704445

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID18139

Diallyl adipate

C12H18O4

HCID66183

Diallyl isophthalate

C14H14O4

结构：C=CCOC(=O)c1cc(C(=O)OCC=C)cc(C(=O)OCC=C)c1

HCID87328

Triallyl trimesate

C18H18O6

$结构：C=CCOC(=O)/C=C\C(=O)OCC=C$

HCID5354266

Diprop-2-en-1-yl (2Z)-but-2-enedioate

C10H12O4

PRODUCTS

生成物

结构：O=C([O-])CCC(=O)OC(C1CC=CCC1)C1CC=CCC1

HCID21324161

未命名化合物

收率 72%

HCID21324164

未命名化合物

收率 59.6%

PROCEDURE

实验过程

Other unsaturated esters which were reacted in a mole ratio of 2 MCP to 1 of ester to form adducts with 1-mercapto-3-chloro-2-propanol are diallyl isophthalate (at 100% reacted under 3 megarads radiation), diallyl maleate, diallyl adipate, di(4-cyclohexenyl)methyl succinate (10 hours exposure to ultraviolet light, 72% yield of brown liquid), diethylene glycol undecylenate (about 10 hours U.V. radiation. 59.6% yield of brown liquid), triallyl trimesate, ##STR19##

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-a1c11f8e9e8443a4bdc7b2b17c941f55
来源数据集: uspto-grants-1978_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04126746
来源说明: uspto-grants-1978_11

反应 SMILES

C([O:15][CH2:16][CH:17]=C)(=O)[C:2]1[CH:13]=[CH:12][CH:11]=[C:4](C(OCC=C)=O)[CH:3]=1.[C:19]([O:29]CC=C)(=[O:28])/[CH:20]=[CH:21]\[C:22]([O:24][CH2:25][CH:26]=[CH2:27])=[O:23].[C:33](OCC=C)(=O)[CH2:34][CH2:35][CH2:36][CH2:37][C:38](OCC=C)=O.C(OCC=C)(=O)[C:50]1[CH:67]=[C:60](C(OCC=C)=O)[CH:59]=[C:52]([C:53]([O:55][CH2:56][CH:57]=C)=[O:54])[CH:51]=1>>[C:22]([O:24][CH:25]([CH:26]1[CH2:27][CH:33]=[CH:34][CH2:35][CH2:36]1)[CH:2]1[CH2:3][CH:4]=[CH:11][CH2:12][CH2:13]1)(=[O:23])[CH2:21][CH2:20][C:19]([O-:29])=[O:28].[C:53]([O:55][CH2:56][CH2:57][O:23][CH2:17][CH2:16][OH:15])(=[O:54])[CH2:52][CH2:59][CH2:60][CH2:67][CH2:50][CH2:51][CH2:38][CH2:37][CH:36]=[CH2:35]