HuagongsheHuagongshe Chemistry Print Report · For research reference only
Aluminum(III) Chloride → cis-2-(3-Methyl-1-oxo-2-butenyl)cyclopentanecarboxylic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Aluminum(III) Chloride | HCID 6451240 | — |
| Reactant | cis-tetrahydro-1H-cyclopenta[c]furan-1,3(4H)-dione | HCID 10920594 | — |
| Solvent | 1,2-Dichloroethane | HCID 11 | — |
| Product | cis-2-(3-Methyl-1-oxo-2-butenyl)cyclopentanecarboxylic acid | HCID 54003608 | — |
Reaction Steps
To a stirred suspension of 4.38 g. (32.86 mmole) of anhydrous aluminum chloride in 100 ml. of 1,2-dichloroethane at room temperature is added 2.30 g. (16.43 mmoles) of cis-1,2-cyclopentanedicarboxylic anhydride. Ethylene is then bubbled through the clear solution with stirring for four hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04206137 |
| Source dataset | uspto-grants-1980_06 |
| ORD ID | ord-3522fd64688e4d348c58640434f43a2d |
| Source note | uspto-grants-1980_06 |