Triethylamine → HCID 178513470, 화합물

HRID 1706083노트

반응식

HRID 1706083 반응식
[N+:1]([C:4]1[CH:15]=[CH:14][C:7]([CH:8]=[CH:9][S:10](Cl)(=[O:12])=[O:11])=[CH:6][CH:5]=1)([O-:3])=[O:2].[N+:16]([C:19]1[CH:27]=[CH:26][C:22]([C:23]([NH2:25])=[NH:24])=[CH:21][CH:20]=1)([O-:18])=[O:17].C(N(CC)CC)C>CC(C)=O>[N+:1]([C:4]1[CH:15]=[CH:14][C:7]([CH:8]=[CH:9][S:10]([NH:25][C:23](=[NH:24])[C:22]2[CH:21]=[CH:20][C:19]([N+:16]([O-:18])=[O:17])=[CH:27][CH:26]=2)(=[O:12])=[O:11])=[CH:6][CH:5]=1)([O-:3])=[O:2]

참가 물질

5

반응물 3

HCID 8471TriethylamineHCID 1174754-NitrobenzamidineHCID 3480064-Nitrostyrylsulfonyl chloride

생성물 1

HCID 178513470HCID 178513470, 화합물

시약·촉매·용매 1

HCID 180Acetone용매

실험 절차

4-Nitrostyrylsulfonyl chloride (2.5 g., 0.01 mole) is added portion-wise to a solution of 4-nitrobenzamidine (1.65 g., 0.01 mole), prepared according to the procedure of L. Weintraub, et al., J. Org. Chem., 33, 1679 (1968), and triethylamine (1.01 g., 0.01 mole) in 50 ml. of acetone at 10° C. After stirring for a period of 1 hr. at 25° C., the mixture is concentrated under reduced pressure and then residual material stirred with water and collected. Triturating the filter cake with acetone provides N-(4-NITROSTYRYLSULFONYL)-4-NITROBENZAMIDINE, m.p. 173°-177° C.

후처리

  1. customprepared
  2. customat 10° C
  3. concentrationat 25° C., the mixture is concentrated under reduced pressure
  4. stirringresidual material stirred with water
  5. customcollected
  6. customTriturating the filter cake with acetone

출처 및 근거

ORD 기록
ord-0fe419b1cc994ceb9c34bd91c0ac197f
출처 데이터셋
uspto-grants-1980_06
특허 번호
US04206142

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