Toluene 2,4-Diisocyanate → Formanilide

HRID 1706248Notes

Reaction equation

HRID 1706248 reaction equation
[N-]=C=O.C[C:5]1[C:6](N=C=O)=[CH:7][C:8]([N:11]=[C:12]=[O:13])=[CH:9][CH:10]=1>>[NH:11]([CH:12]=[O:13])[C:8]1[CH:9]=[CH:10][CH:5]=[CH:6][CH:7]=1

Participants

3

Reactant 2

HCID 11443Toluene 2,4-DiisocyanateHCID 105034Isocyanate

Product 1

HCID 7671Formanilide

Procedure

41.4 parts, by weight, of an isocyanate mixture consisting of 40%, by weight, of a tolylene diisocyanate mixture (2,4- and 2,6-isomer in proportions of 65:35) and 60%, by weight, of a polyphenyl-polymethylene polyisocyanate (viscosity approximately 200 cP at 25° C.). The polyphenyl-polymethylene polyisocyanate was obtained by anilineformaldehyde condensation followed by phosgenation.

Sources & evidence

ORD record
ord-232793d454d0423b929ba02c5018819a
Source dataset
uspto-grants-1980_06
Patent number
US04206289

Reaction notes

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