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HRID1706674

反应详情

EQUATION

反应方程式

HRID 1706674 的结构方程式

REACTANTS

反应物

1
结构：CCCCCCC(C)(C)c1cc(O)c2c(c1)OC(C)(C)[C@@H]1CCC(=O)C[C@H]21
HCID86735145

未命名化合物

PRODUCTS

生成物

1
结构：CCCCCCC(C)(C)c1cc(O)c2c(c1)OC(C)(C)[C@@H]1CCC(=O)C[C@@H]21
HCID5284592

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：ClC(Cl)Cl
溶剂HCID6212

Chloroform

CHCl3

PROCEDURE

实验过程

Evaporation of the solvent from eluates shown by thin layer chromatography to contain a different component afforded 55 mg. of (-)-cis-1-hydroxy-3-(1,1-dimethylheptyl)-6,6-dimethyl-6,6a,7,8,10,10a-hexahydro-9H-dibenzo-[b,d]pyran-9-one. [α]20D-50° (c=1.0, CHCl3).

WORKUP

后处理

  1. customEvaporation of the solvent from eluates
  2. customafforded 55 mg