Sodium Hydroxide → HCID 86736347, compound

Participants

Reaction Conditions

Reaction Steps

A 100 ml four-necked flask fitted with a stirrer, thermometer, addition funnel and gas inlet was charged with 24.1 g (0.08 m) of 6-hydroxyhexyl perfluoroisopropyl ether, cooled under nitrogen to 15° C. and held for one half hour. Chlorosulfonic acid (10.3 g, 0.08 m) was added over a period of 30 minutes with stirring while maintaining the temperature at 15°-20° C., reaction was quite exothermic. Stirring was continued for one hour when the addition was completed. The reaction mixture was poured into a solution of 6.9 g of 50% sodium hydroxide in 68 g of cold water. The resulting solution was clear and colorless containing 27.2% by weight of 6-hydroxy perfluoroisopropyl ether sodium sulfate and was designated as Product I (A).

Provenance & Evidence