Hydroxide → HCID 86737060, compound

HRID 1706847Notes

Reaction equation

HRID 1706847 reaction equation
[CH:1]1[C:6]([CH:7]=O)=[CH:5][C:4]2[O:9][CH2:10][O:11][C:3]=2[CH:2]=1.[C:12]([N:17]1[CH2:22][CH2:21][CH2:20][CH2:19][CH2:18]1)(=[O:16])/[CH:13]=[CH:14]/[CH3:15].[OH-]>>[CH:7](=[CH:15]/[CH:14]=[CH:13]/[C:12]([N:17]1[CH2:22][CH2:21][CH2:20][CH2:19][CH2:18]1)=[O:16])[C:6]1[CH:1]=[CH:2][C:3]2[O:11][CH2:10][O:9][C:4]=2[CH:5]=1

Participants

4

Reactant 3

HCID 961HydroxideHCID 8438PiperonalHCID 53724133626-69-5

Product 1

HCID 86737060HCID 86737060, compound

Procedure

1 mol of piperonal is reacted with 1.1 mols of crotonic acid piperidide in the presence of 0.09 mol of a hydroxide, indicated in Table 2 below, under the reaction conditions described in Example 1 to give piperonylidenecrotonic acid piperidide. The yields obtained are likewise indicated in Table 2.

Workup

  1. customunder the reaction conditions

Sources & evidence

ORD record
ord-99ad1f2b3a5247e49779e91155fc519c
Source dataset
uspto-grants-1980_06
Patent number
US04209445

Reaction notes

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