Sodium Hydroxide → HCID 86737064, compound

HRID 1706861Notes

Reaction equation

HRID 1706861 reaction equation
C([O:3][C:4](=[O:32])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][C@@H:11]1[C@@H:15]([CH:16]=[CH:17][C:18]23[O:31][CH2:30][CH2:29][O:28][C:19]2([O:24][CH2:25][CH2:26][O:27]3)[CH2:20][CH2:21][CH2:22][CH3:23])[CH2:14][CH2:13][CH2:12]1)C.O1CCOCC1.[OH-].[Na+]>O>[CH2:26]1[CH2:25][O:24][C:19]2([O:28][CH2:29][CH2:30][O:31][C:18]2([CH:17]=[CH:16][C@@H:15]2[C@@H:11]([CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][C:4]([OH:32])=[O:3])[CH2:12][CH2:13][CH2:14]2)[O:27]1)[CH2:20][CH2:21][CH2:22][CH3:23]

Participants

5

Reactant 3

HCID 14798Sodium HydroxideHCID 312751,4-DioxaneHCID 86737061HCID 86737061, compound

Product 1

HCID 86737064HCID 86737064, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture of 0.9 g of 9,9;15,15-bis-(ethylenedioxy)-13-prostenoic acid ethyl ester, 60 ml of dioxan, 40 ml of H2O and 0.08 g of NaOH is boiled for 2 hours. The solvent is distilled. After recrystallization of the residue from methanol, the sodium salt of 9,9;15,15-bis-(ethylenedioxy)-13-prostenoic acid is obtained.

Workup

  1. distillationThe solvent is distilled
  2. customAfter recrystallization of the residue from methanol

Sources & evidence

ORD record
ord-2eb4b45fcfdb45c5a2885bb5641b1ff1
Source dataset
uspto-grants-1980_06
Patent number
US04209444

Reaction notes

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