HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Butanol → HCID 20332621, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Butanol | HCID 263 | — |
| Reactant | p-Toluenesulfonic acid | HCID 6101 | — |
| Reactant | p-Chlorophenacyl bromide | HCID 68303 | — |
| Reactant | (2,4-Dichlorophenyl)ethane-1,2-diol | HCID 13084216 | — |
| Solvent | Benzene | HCID 241 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 20332621 | HCID 20332621 | — |
Reaction Steps
A mixture of 11.6 parts of 2-bromo-4'-chloroacetophenone, 12.4 parts of 1-(2,4-dichlorophenyl)-1,2-ethanediol, 0.1 parts of p-toluenesulfonic acid, 80 parts of n-butanol and 160 parts of benzene in stirred and refluxed for 24 hours with water-separator. The solvent is removed in vacuo and the residue is triturated in methanol. The precipitated product is filtered off and crystallized from petroleum ether, yielding 2-(bromomethyl)-2-(p-chlorophenyl)-4-(2,4-dichlorophenyl)-1,3-dioxolane; m.p. 82.7° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04209447 |
| Source dataset | uspto-grants-1980_06 |
| ORD ID | ord-3ac521427b3e4f0db399f6839eda5a5e |
| Source note | uspto-grants-1980_06 |