1-Chloro-4-(chloromethyl)benzene → HCID 10251184, compound

HRID 1706940Notes

Reaction equation

HRID 1706940 reaction equation
[CH2:1]([O:3][C:4](=[O:18])[CH2:5][N:6]1[C:10]2[CH:11]=[C:12]([Cl:16])[C:13]([Cl:15])=[CH:14][C:9]=2[NH:8][C:7]1=[O:17])[CH3:2].[Cl:19][C:20]1[CH:27]=[CH:26][C:23]([CH2:24]Cl)=[CH:22][CH:21]=1>>[CH2:1]([O:3][C:4](=[O:18])[CH2:5][N:6]1[C:10]2[CH:11]=[C:12]([Cl:16])[C:13]([Cl:15])=[CH:14][C:9]=2[N:8]([CH2:24][C:23]2[CH:26]=[CH:27][C:20]([Cl:19])=[CH:21][CH:22]=2)[C:7]1=[O:17])[CH3:2]

Participants

3

Reactant 2

HCID 77231-Chloro-4-(chloromethyl)benzeneHCID 10108207HCID 10108207, compound

Product 1

HCID 10251184HCID 10251184, compound

Procedure

The procedure described in Example 1 was repeated (using the same molar proportions as before) except that 240 mg. (0.0008 mole) of 5,6-dichloro-2-oxo-1-benzimidazolineacetic acid ethyl ester and 134 mg. (0.00083 mole) of p-chlorobenzyl chloride were reacted to afford 3-(p-chlorobenzyl)-5,6-dichloro-2-oxo-1-benzimidazolineacetic acid ethyl ester as the desired final product.

Sources & evidence

ORD record
ord-68cd717aabe34625b8597a8cf11d4c15
Source dataset
uspto-grants-1980_06
Patent number
US04209527

Reaction notes

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