Phosphorus pentachloride → HCID 86734754, compound

HRID 1707171Notes

Reaction equation

HRID 1707171 reaction equation
[Cl:1][CH:2]([Cl:17])[C:3]([O:5][N:6]=[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]1[CH2:13][C:14](O)=[O:15])=[O:4].P(Cl)(Cl)(Cl)(Cl)[Cl:19]>C(Cl)Cl>[Cl:1][CH:2]([Cl:17])[C:3]([O:5][N:6]=[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]1[CH2:13][C:14]([Cl:19])=[O:15])=[O:4]

Participants

4

Reactant 2

HCID 24819Phosphorus pentachlorideHCID 86733035HCID 86733035, compound

Product 1

HCID 86734754HCID 86734754, compoundYield 100%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

To a suspension of 2-dichloroacetoxyiminophenylacetic acid (syn-isomer) (0.276 g) in methylene chloride (10 ml.) was added phosphorus pentachloride (0.208 g) and the mixture was stirred for one hour at room temperature, during which time solution took place. After removal of solvent under reduced pressure, benzene was evaporated from the residue, and the resulting oil freed from solvent under vacuum, giving 2-dichloroacetoxyiminophenylacetyl chloride (syn-isomer) (0.29 g., 100%), νmax. (liquid film) 1770 cm.-1 (COCl and CO2R).

Workup

  1. customAfter removal of solvent under reduced pressure, benzene
  2. customwas evaporated from the residue

Sources & evidence

ORD record
ord-cc5c96595e12424b945c710df710a2b7
Source dataset
uspto-grants-1980_06
Patent number
US04209616

Reaction notes

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