6,10-Dimethyl-11-(benzoyl)oxy 5,9-undecadien-2-one → HCID 131718159, compound

HRID 1707777Notes

Reaction equation

HRID 1707777 reaction equation
[CH3:1][C:2]([CH2:9][CH2:10][CH:11]=[C:12]([CH3:18])[CH2:13][O:14][C:15](=[O:17])[CH3:16])=[CH:3][CH2:4][CH2:5][C:6](=[O:8])[CH3:7].[CH3:19][C:20](CCC=C(C)COC(=O)C1C=CC=CC=1)=CCCC(=O)C>>[CH3:7][C:6]([OH:8])([CH2:5][CH2:4][CH:3]=[C:2]([CH3:1])[CH2:9][CH2:10][CH:11]=[C:12]([CH3:18])[CH2:13][O:14][C:15](=[O:17])[CH3:16])[C:19]#[CH:20]

Participants

3

Reactant 2

HCID 536426586,10-Dimethyl-11-(benzoyl)oxy 5,9-undecadien-2-oneHCID 53852708HCID 53852708, compound

Product 1

HCID 131718159HCID 131718159, compound

Procedure

The procedure described in Example 9 was repeated except that 6,10-dimethyl-11-acetoxy-5,9-undecadien-2-on or 6,10-dimethyl-11-(benzoyl)oxy-5,9-undecadien-2-one was employed as a starting material to give 3,7,11-trimethyl-12-acetoxy-6,10-dodecadien-1-in-3-ol and 3,7,11-trimethyl-12-(benzoyl)oxy-6,10-dodecadien-l-in-3-ol.

Sources & evidence

ORD record
ord-21eecf2a33314c91b7edcc2b0d195acd
Source dataset
uspto-grants-1994_10
Patent number
US05354874

Reaction notes

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