HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ammonia → 4-Amino-3,3-dimethylbutyltrimethoxysilane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ammonia | HCID 222 | — |
| Reactant | 3-Cyano-3-methylbutyltrimethoxysilane | HCID 18962608 | — |
| Catalyst | Nickel | HCID 935 | — |
| Product | 4-Amino-3,3-dimethylbutyltrimethoxysilane | HCID 21939033 | — |
Reaction Steps
In accordance with the procedure in Example 7, 3-cyano-3-methylbutyltrimethoxysilane (600 grams, 2.76 moles) was hydrogenated in the presence of 10.0 grams of ammonia and 8.0 grams of nickel (5%) on kieselguhr. The yield after distillation (boiling point, 68° C. at 0.25 mm Hg) was 590 grams of 4-amino-3,3-dimethylbutyltrimethoxysilane (96.6%). The material was characterized by infra-red, 1H and 13C NMR spectroscopy.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05354880 |
| Source dataset | uspto-grants-1994_10 |
| ORD ID | ord-9ac4e3d133ef4dbdafa53235410dea56 |
| Source note | uspto-grants-1994_10 |