Ethanol, 2-amino-, 1-nitrate, nitrate (1:1) → HCID 18961061, compound

HRID 1708185Notes

Reaction equation

HRID 1708185 reaction equation
[N+]([O-])(O)=O.[N+:5]([O:8][CH2:9][CH2:10][NH2:11])([O-:7])=[O:6].[N+:12]([C:15]1[CH:16]=[C:17]([CH:21]2[S:25][C:24](=[O:26])[NH:23][CH:22]2[C:27](O)=[O:28])[CH:18]=[CH:19][CH:20]=1)([O-:14])=[O:13]>>[N+:5]([O:8][CH2:9][CH2:10][NH:11][C:27]([CH:22]1[CH:21]([C:17]2[CH:18]=[CH:19][CH:20]=[C:15]([N+:12]([O-:14])=[O:13])[CH:16]=2)[S:25][C:24](=[O:26])[NH:23]1)=[O:28])([O-:7])=[O:6]

Participants

3

Reactant 2

HCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)HCID 18961038HCID 18961038, compound

Product 1

HCID 18961061HCID 18961061, compoundYield 67.8%

Procedure

A procedure similar to that described in Example 1 was repeated, but using 380 mg of N-(2-nitrooxyethyl)amine nitrate and 500 mg of 5-(3-nitrophenyl)-2-oxothiazolidine-4-carboxylic acid, to obtain 450 mg of the title compound as a pale yellow powder.

Sources & evidence

ORD record
ord-194753eb34774534b014d19cb2c03dcd
Source dataset
uspto-grants-1994_10
Patent number
US05356918

Reaction notes

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