Ethanol, 2-amino-, 1-nitrate, nitrate (1:1) → HCID 18961042, compound

HRID 1708187Notes

Reaction equation

HRID 1708187 reaction equation
[N+]([O-])(O)=O.[N+:5]([O:8][CH2:9][CH2:10][NH2:11])([O-:7])=[O:6].[Cl:12][C:13]1[CH:18]=[CH:17][C:16]([CH:19]2[S:23][C:22](=[O:24])[NH:21][CH:20]2[C:25](O)=[O:26])=[CH:15][CH:14]=1>>[N+:5]([O:8][CH2:9][CH2:10][NH:11][C:25]([CH:20]1[CH:19]([C:16]2[CH:15]=[CH:14][C:13]([Cl:12])=[CH:18][CH:17]=2)[S:23][C:22](=[O:24])[NH:21]1)=[O:26])([O-:7])=[O:6]

Participants

3

Reactant 2

HCID 78397Ethanol, 2-amino-, 1-nitrate, nitrate (1:1)HCID 18961069HCID 18961069, compound

Product 1

HCID 18961042HCID 18961042, compound

Procedure

A procedure similar to that described in Example 1 was repeated, but using 394 mg of N-(2-nitrooxyethyl)amine nitrate and 500 mg of 5-(4-chlorophenyl)-2-oxothiazolidine-4-carboxylic acid, to obtain 350 mg of the title compound as colorless needles, melting at 125°-127° C. (after recrystallization from methylene chloride).

Workup

  1. customto obtain
  2. custom350 mg of the title compound as colorless needles, melting at 125°-127° C. (after recrystallization from methylene chloride)

Sources & evidence

ORD record
ord-b423cae356ad4a668b521e94346bcfe8
Source dataset
uspto-grants-1994_10
Patent number
US05356918

Reaction notes

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