HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethyl Sulfoxide → Hydrogen Peroxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethyl Sulfoxide | HCID 679 | — |
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Aniline | HCID 6115 | — |
| Solvent | Water | HCID 962 | — |
| Product | Hydrogen Peroxide | HCID 784 | — |
| Product | Azobenzene | HCID 2272 | — |
Reaction Steps
The excess hydroxide ion (OH-), dissolved dioxygen (O2), and aniline (PhNH2) reacted in the dimethyl sulfoxide solution to form superoxide ion (O2-.), azobenzene (PhN=NPh), hydrogen peroxide (HOOH), and water (H2O). The dioxygen was introduced by bubbling gaseous dioxygen through the solution of other reactants for 20 minutes, and then purging with argon. The reaction yielded concentrations of 1.4 mM of superoxide ion and 2.5 mM of azobenzene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05358657 |
| Source dataset | uspto-grants-1994_10 |
| ORD ID | ord-3ce4a3b51812440f8ef70fce014e2aaa |
| Source note | uspto-grants-1994_10 |