HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Tetrafluoroborate → Dibenzylhydroxylamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Tetrafluoroborate | HCID 4343483 | — |
| Reactant | HCID 15219400 | HCID 15219400 | — |
| Product | Dibenzylhydroxylamine | HCID 69297 | 82% |
Reaction Steps
tert-Butyldimethylsiloxy-N,N-dibenzylamine, Compound 1, was heated with sodium tetrafluoroborate at about 200° C. for 30 minutes. The tert-butyldimethylfluorosilane could be distilled off at 62°-64° C. in 82% yield. N,N-dibenzylhydroxylamine was isolated from the reaction. Similar results were obtained using sodium salts of hexafluorophosphate and hexafluoroantimonate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05358843 |
| Source dataset | uspto-grants-1994_10 |
| ORD ID | ord-b27a97d95ac2474980480dfa4329a26b |
| Source note | uspto-grants-1994_10 |