HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetone → Di-tert-butyl peroxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetone | HCID 180 | — |
| Reactant | Methanol | HCID 887 | — |
| Reactant | tert-Butyl hydroperoxide | HCID 6410 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Catalyst | Platinum | HCID 23939 | — |
| Product | tert-Butyl hydroperoxide | HCID 6410 | — |
| Product | Di-tert-butyl peroxide | HCID 8033 | 5% |
Reaction Steps
A 19.1% solution of TBHP in TBA decomposed over a commercial 0.15% Pd, 0.15% Pt on alumina gave (80° C., 0.5 space velocity) 74.2 TBHP conversion with selectivity to TBA of 84.1%, DTBP 5.0%, acetone 10.9%, and methanol 2.6%. Minor products including carboxylic acids were also formed.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05359130 |
| Source dataset | uspto-grants-1994_10 |
| ORD ID | ord-fd977b37831c4c90b55673b5b63fe669 |
| Source note | uspto-grants-1994_10 |