HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tatb → 1,3,5-Trichloro-2,4,6-trinitrobenzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tatb | HCID 18286 | — |
| Reactant | Thionyl Chloride | HCID 24386 | — |
| Reactant | 1,3-Dichloro-5-methoxy-2,4,6-trinitrobenzene | HCID 14794057 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 1,3,5-Trichloro-2,4,6-trinitrobenzene | HCID 17518 | — |
Reaction Steps
Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) from 3,5-dichloroanisole. Nitration of 3,5-dichloroanisole under relatively mild conditions gave 3,5-dichloro-2,4,6-trinitroanisole in high yield and purity. Ammonolysis of this latter compound gave the desired TATB. Another route to TATB was through the treatment of the 3,5-dichloro-2,4,6-trinitroanisole with thionyl chloride and dimethylformamide to yield 1,3,5-trichloro-2,4,6-trinitrobenzene. Ammonolysis of this product produced TATB.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04952733 |
| Source dataset | uspto-grants-1990_08 |
| ORD ID | ord-050e3d1922244ccebb6f81e24bc06f66 |
| Source note | uspto-grants-1990_08 |