Propylene → HCID 67237864, compound

HRID 1712110Notes

Reaction equation

HRID 1712110 reaction equation
[OH:1][CH2:2]/[C:3](/[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)=[CH:4]/[N+:5]([O-:7])=[O:6].C=CC>>[OH:1][CH2:2][CH:3]([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[CH2:4][N+:5]([O-:7])=[O:6]

Participants

3

Reactant 2

HCID 8252PropyleneHCID 67237855HCID 67237855, compound

Product 1

HCID 67237864HCID 67237864, compoundYield 55%

Procedure

The same procedure as Example 17, except that (E)-3-hydroxy-1-nitro-2-phenyl-1-propene was used in place of (E)-1-nitro-2-(pyridin: 2-yl)-1-propene, provided optically active 3-hydroxy-1-nitro-2-phenylpropane.

Sources & evidence

ORD record
ord-b9b7346de8284bb4bad2b02fab63ce98
Source dataset
uspto-grants-2010_09
Patent number
US07790900B2

Reaction notes

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