HRID171338

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID813

Potassium cation

K+

HCID74506

Triphenylmethylphosphonium

C19H18P+

HCID4574913

未命名化合物

结构：COC(=O)c1cccc(C(=O)c2ccc3c(c2)C(C)(C)CCC3(C)C)c1

HCID21185922

未命名化合物

PRODUCTS

生成物

结构：C=C(c1cccc(C(=O)OC)c1)c1ccc2c(c1)C(C)(C)CCC2(C)C

HCID21185885

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-2351c5a9b49e4f369069a2652b33b83d
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (9/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (9/10)

反应 SMILES

[Br-:33].[CH3:1][C:2]([CH3:3])([O-:4])[CH3:5].[CH3:34][P+:35]([c:36]1[cH:37][cH:38][cH:39][cH:40][cH:41]1)([c:42]1[cH:43][cH:44][cH:45][cH:46][cH:47]1)[c:48]1[cH:49][cH:50][cH:51][cH:52][cH:53]1.[CH3:7][C:8]1([CH3:32])[c:9]2[cH:10][cH:11][c:12]([C:20](=[O:21])[c:22]3[cH:23][c:24]([C:25](=[O:26])[O:27][CH3:28])[cH:29][cH:30][cH:31]3)[cH:13][c:14]2[C:15]([CH3:18])([CH3:19])[CH2:16][CH2:17]1.[K+:6]>>[CH2:1]=[C:20]([c:12]1[cH:11][cH:10][c:9]2[c:14]([cH:13]1)[C:15]([CH3:18])([CH3:19])[CH2:16][CH2:17][C:8]2([CH3:7])[CH3:32])[c:22]1[cH:23][c:24]([C:25](=[O:26])[O:27][CH3:28])[cH:29][cH:30][cH:31]1