HuagongsheHuagongshe Chemistry Print Report · For research reference only
Allyltrimethylsilane → (2S,3R,4S,5R,6R)-2-allyl-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)-2-(4-chloro-5-(4-ethylbenzyl)-2-methoxyphenyl)tetrahydro-2H-pyran
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Allyltrimethylsilane | HCID 69808 | — |
| Reactant | HCID 68794922 | HCID 68794922 | — |
| Product | (2S,3R,4S,5R,6R)-2-allyl-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)-2-(4-chloro-5-(4-ethylbenzyl)-2-methoxyphenyl)tetrahydro-2H-pyran | HCID 68789901 | 159.5% |
Reaction Steps
The title compound (230 mg, 80%) was prepared from 23 (280 mg) and allyltrimethylsilane (167 μL, 120 mg, 3.0 eq.) using the method described for preparing 24.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07795228B2 |
| Source dataset | uspto-grants-2010_09 |
| ORD ID | ord-0636fb2842634f318caaa48d9b6ba32a |
| Source note | uspto-grants-2010_09 |