HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl (4'-nitrobiphenyl-4-yl)malonate → Diethyl (4'-aminobiphenyl-4-yl)malonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl (4'-nitrobiphenyl-4-yl)malonate | HCID 59464037 | — |
| Reactant | Methyl 3-(4-aminophenyl)cyclopentanecarboxylate | HCID 59464327 | — |
| Product | Diethyl (4'-aminobiphenyl-4-yl)malonate | HCID 59464212 | — |
Reaction Steps
Diethyl (4′-nitrobiphenyl-4-yl)malonate was reduced by the method of Intermediate 84, step (ii), to give the title compound; 1H NMR δ 1.17-1.22 (6H, m), 4.10-4.22 (4H, m), 4.92 (1H, s), 5.22 (2H, s), 6.63-6.66 (2H, m), 7.35-7.38 (4H, m), 7.52-7.54 (2H, m); MS m/e MH+ 328.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07795283B2 |
| Source dataset | uspto-grants-2010_09 |
| ORD ID | ord-e80de2909a72483ca826854d712d4c70 |
| Source note | uspto-grants-2010_09 |