HuagongsheHuagongshe Chemistry Print Report · For research reference only
Nitrogen → HCID 57539290, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Nitrogen | HCID 947 | — |
| Reactant | Di-tert-butylchlorophosphine | HCID 139566 | — |
| Reactant | 2-(4-Bromophenyl)-1,3-dioxolane | HCID 2773842 | — |
| Reactant | (4-tert-Butyl-phenyl)-phenyl-amine | HCID 11447459 | — |
| Reactant | Sodium t-butoxide | HCID 23676156 | — |
| Catalyst | palladium(II) acetate | HCID 167845 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 57539290 | HCID 57539290 | — |
Reaction Steps
48.8 g (213 mmol) of 2-(4-bromophenyl)-1,3-dioxolane and 48 g (213 mmol) of (4-tert-butylphenyl)phenylamine are initially introduced in 750 ml of toluene, and the solution is saturated with N2 for about 30 min. 29.2 g (304 mmol) of sodium tert-butoxide are subsequently added in small portions, followed by 760 mg (4.2 mmol) of chlorobis-t-butylphosphine and 485 mg (2.1 mmol) of Pd(OAc)2. The mixture is refluxed for 3 h with monitoring by TLC.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07799875B2 |
| Source dataset | uspto-grants-2010_09 |
| ORD ID | ord-781e685e02d04d64bfe036c7f50e2677 |
| Source note | uspto-grants-2010_09 |