4,4'-Dibromobenzil → HCID 22638476, compound

HRID 1715530Notes

Reaction equation

HRID 1715530 reaction equation
[NH2:1][C:2]1[C:7]([NH2:8])=[CH:6][CH:5]=[CH:4][C:3]=1[N+:9]([O-:11])=[O:10].[Br:12][C:13]1[CH:18]=[CH:17][C:16]([C:19]([C:21]([C:23]2[CH:28]=[CH:27][C:26]([Br:29])=[CH:25][CH:24]=2)=O)=O)=[CH:15][CH:14]=1>C(O)(=O)C.CO>[Br:12][C:13]1[CH:14]=[CH:15][C:16]([C:19]2[C:21]([C:23]3[CH:24]=[CH:25][C:26]([Br:29])=[CH:27][CH:28]=3)=[N:1][C:2]3[C:7](=[CH:6][CH:5]=[CH:4][C:3]=3[N+:9]([O-:11])=[O:10])[N:8]=2)=[CH:17][CH:18]=1

Participants

5

Reactant 2

HCID 964304,4'-DibromobenzilHCID 43595253-Nitro-1,2-phenylenediamine

Product 1

HCID 22638476HCID 22638476, compound

Reagents, catalysts & solvents 2

HCID 176Acetic AcidSolventHCID 887MethanolSolvent

Procedure

1.53 g (10 mmol) of 2,3-diaminonitrobenzene and 3.68 g (10 mmol) of 4,4′-dibromobenzil were dissolved in 80 g of a mixed solvent of acetic acid and methanol (1:1) and reacted at a reaction temperature of 70° C. for 30 hours. After completion of the reaction, the solvent was removed and a reaction product was extracted by means of a silica gel.

Workup

  1. customreacted at a reaction temperature of 70° C. for 30 hours
  2. customAfter completion of the reaction
  3. customthe solvent was removed
  4. extractiona reaction product was extracted by means of a silica gel

Sources & evidence

ORD record
ord-faccca78210e43808c55dd28557ab5c9
Source dataset
uspto-grants-2010_09
Patent number
US07799894B2

Reaction notes

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