Toluene → 2,3,5-Triiodobenzoic acid
Reaction equation
[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12].CCCCCCCCCC(C)C.C1(C)C=CC=CC=1>>[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12]Participants
3
Procedure
17 mL of TIBA/isododecane solution (110 g/L) were mixed with 3.7 mL of MAO/toluene solution (Albemarle 30% wt/wt, d=0.92 g/mL, 17.6 mmol MAO) to obtain a MAO/TIBA molar ratio of 1.8:1. The solution was stirred for 1 h at room temperature. Then, 52.6 mg of C-2 were dissolved in the solution. The solution did not show any trace of residual solid. The final solution was diluted with 9.5 mL of isododecane to reach a concentration of 98 gTOT/L and 1.74 gmetallocene/L.
Sources & evidence
- ORD record
- ord-3e1ed20401ca4aafa62e96e20b00a4b2
- Source dataset
- uspto-grants-2010_09
- Patent number
- US07803887B2
Reaction notes
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