HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanesulfenylchloride → 1-[(Chloromethoxy)methyl]naphthalene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanesulfenylchloride | HCID 138595 | — |
| Reactant | 1-{[(Methylsulfanyl)methoxy]methyl}naphthalene | HCID 15650475 | — |
| Reactant | HCID 22556242 | HCID 22556242 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 1-[(Chloromethoxy)methyl]naphthalene | HCID 13408288 | — |
Reaction Steps
1-Chloromethyloxymethyl)naphthalene Sulfuryl chloride (12 mmol) in dry dichloromethane (20 mmol) was added dropwise with stirring to a solution of methylthiomethyl 1-naphthylmethyl ether (12 mmol) in dry dichloromethane (40 ml) at room temperature. After stirring for 30 min the solvent and methanesulfenyl chloride formed in the reaction were distilled off at reduced pressure. The residual material was used for alkylation without further purification. 1H NMR (CDCl3): δ5.13 (CH2), 5.47 (CH2Cl), 7.2-8.3 (Naph).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04539324 |
| Source dataset | uspto-grants-1985_09 |
| ORD ID | ord-a69b9863163d4784871dc425371f3af4 |
| Source note | uspto-grants-1985_09 |