2-Methoxynaphthalene → HCID 13231058, compound

HRID 1719370Notes

Reaction equation

HRID 1719370 reaction equation
[CH3:1][O:2][C:3]1[CH:12]=[CH:11][C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=1.[C:13]1([S:19]([O:22][C@@H:23]([CH3:27])[C:24](Cl)=[O:25])(=[O:21])=[O:20])[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>>[CH3:1][O:2][C:3]1[CH:4]=[C:5]2[C:10](=[CH:11][CH:12]=1)[CH:9]=[C:8]([C:24](=[O:25])[C@@H:23]([O:22][S:19]([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)(=[O:21])=[O:20])[CH3:27])[CH:7]=[CH:6]2

Participants

3

Reactant 2

HCID 71192-MethoxynaphthaleneHCID 13186839(2S)-1-Chloro-1-oxopropan-2-yl benzenesulfonate

Product 1

HCID 13231058HCID 13231058, compound

Procedure

In the same manner as described in Example 10 but using β-methoxynaphthalene and (S)-2-(benzenesulfonyloxy)-propionyl chloride, (S)-1-(6-methoxy-2-naphthyl)-2-benzenesulfonyloxy-1-propanone was obtained as colorless crystals.

Sources & evidence

ORD record
ord-2eb78cb0ee70463db2ce0ea8c396d2a9
Source dataset
uspto-grants-1985_09
Patent number
US04539420

Reaction notes

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