Acetone → HCID 20267325, compound

HRID 1719614Notes

Reaction equation

HRID 1719614 reaction equation
[CH3:1][C:2]([CH3:4])=[O:3].[C:5]1(=O)[CH2:10][CH2:9]C[CH2:7][CH2:6]1.[CH:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1.[OH:18][C:19]1[C:32]2[C:31](=[O:33])[C:30]3C(=[C:26]([NH:41][CH2:42][CH2:43][N:44]=[C:45]([CH3:47])C)[CH:27]=[CH:28][C:29]=3[NH:34][CH2:35][CH2:36][N:37]=[C:38](C)C)C(=O)C=2[C:22]([OH:49])=[CH:21][CH:20]=1>C1(C)C=CC=CC=1>[CH:45](=[N:44][CH2:43][CH2:42][NH:41][C:26]1[C:4]2[C:2](=[O:3])[C:1]3[C:32](=[C:19]([OH:18])[CH:20]=[CH:21][C:22]=3[OH:49])[C:31](=[O:33])[C:30]=2[C:29]([NH:34][CH2:35][CH2:36][N:37]=[CH:38][CH2:12][CH2:17][CH2:16][CH2:15][CH2:14][CH3:13])=[CH:28][CH:27]=1)[CH2:47][CH2:7][CH2:6][CH2:5][CH2:10][CH3:9]

Participants

6

Reactant 4

HCID 180AcetoneHCID 241BenzeneHCID 7967CyclohexanoneHCID 20267323HCID 20267323, compound

Product 1

HCID 20267325HCID 20267325, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

When acetone and cyclohexanone were substituted for the aldehyde precursor in the general procedure for Examples 3-20 and the solvent was benzene or toluene the following compounds were obtained: 1,4-Dihydroxy-5,8-bis[[2-[(1-methylethylidene)amino]ethyl]amino]-9,10-anthracenedione;

Workup

  1. customwere obtained

Sources & evidence

ORD record
ord-32d803f8b24d43f7b6c144fd1d6ba2e6
Source dataset
uspto-grants-1985_09
Patent number
US04540788

Reaction notes

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