Water → HCID 86740303, compound

HRID 1719660Notes

Reaction equation

HRID 1719660 reaction equation
[CH2:1]([C:13]12[S:20][C:14]1([OH:19])[CH:15]=[CH:16][CH:17]=[CH:18]2)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[B:21]([OH:24])([OH:23])[OH:22].O>C1(C)C=CC=CC=1>[O:19]1[CH:15]([CH2:16][CH2:17][CH2:18][CH2:13][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH2:14]1.[B:21]([OH:24])([OH:23])[OH:22].[CH2:1]([C:13]12[S:20][C:14]1([OH:19])[CH:15]=[CH:16][CH:17]=[CH:18]2)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

Participants

5

Reactant 3

HCID 962WaterHCID 7628Boric AcidHCID 86740304HCID 86740304, compound

Product 1

HCID 86740303HCID 86740303, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

Approximately 60 g of 1,2-epoxyhexadeacane (obtained from Union Carbide Co.), 135 g of 50% dodecylphenol sulfide (made by reacting 3 moles of dodecylphenol with 2 moles of sulfur dichloride at 100° to 150° C. for 6 hours with agitation followed by vacuum topping to remove residual HCl) in 100" solvent paraffinic neutral lubricating diluent oil, 100 g of toluene solvent and 20 g of boric acid were charged to a reactor equipped with agitator, heater, Dean-Start tube with condenser and provision for maintaining an inert nitrogen atmosphere. The reactor contents were heated up to 170° C. over a period of 6 hours until water evolution ceased. The solvent was removed by distillation under reduced pressure and the product was then filtered through diatomaceous earth.

Workup

  1. customequipped with agitator, heater, Dean-Start tube with condenser
  2. temperatureprovision for maintaining an inert nitrogen atmosphere
  3. customThe solvent was removed by distillation under reduced pressure
  4. filtrationthe product was then filtered through diatomaceous earth

Sources & evidence

ORD record
ord-91d71601c4d54b2c89969ab494a2cb16
Source dataset
uspto-grants-1985_09
Patent number
US04541942

Reaction notes

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