HRID1719773

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID20243757

未命名化合物

$结构：CC1(C)[C@H](C(=O)OCc2ccccc2)[C@@H]1/C=C\C(=O)O$

HCID86740331

未命名化合物

PRODUCTS

生成物

$结构：CC1(C)[C@H](C(=O)OCc2ccccc2)[C@@H]1/C=C\C(=O)OCC(F)F$

HCID13335665

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6212

Chloroform

CHCl3

PROCEDURE

实验过程

Using the procedure of Example 53, difluoro-ethanol and the product of Step B of Example 57 were reacted to obtain benzyl (1R,cis,Z) 2,2-dimethyl-3-[3-oxo-3-(2,2-difluoroethoxy)-1-propenyl]-cyclopropane-carboxylate with a specific rotation of [α]D20 =+52° (c=0.2% in chloroform).