HuagongsheHuagongshe Chemistry Print Report · For research reference only
tert-Butyl hydroperoxide → (3-Chloro-2,4,6-trimethylbenzoyl)diphenylphosphine oxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | tert-Butyl hydroperoxide | HCID 6410 | — |
| Reactant | Acetylacetonate | HCID 5460482 | — |
| Reactant | alpha-Hydroxy-(3-chloro-2,4,6-trimethylbenzyl)-diphenyl phosphine oxide | HCID 86749383 | — |
| Catalyst | Sodium orthovanadate | HCID 61671 | — |
| Solvent | Chlorobenzene | HCID 7964 | — |
| Product | (3-Chloro-2,4,6-trimethylbenzoyl)diphenylphosphine oxide | HCID 22420311 | 81% |
Reaction Steps
To 15.4 g (0.04 mol) of α-hydroxy-(3-chloro-2,4,6-trimethylbenzyl)-diphenyl phosphine oxide and 0.4 S (1.5mmol) of vanadyl (IV) bis-acetylacetonate in 100 g of chlorobenzene there were added 8.2 g (0.06 mol) of 70w t% strength aqueous tert-butylhydroperoxide and isolated by crystallization following a period of 20 h. Yield: 81%, mp 125°-126° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05504236 |
| Source dataset | uspto-grants-1996_04 |
| ORD ID | ord-c6407c3bd2cd4c85aaffa930feb700ae |
| Source note | uspto-grants-1996_04 |