Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
tert-Butyl hydroperoxide → HCID 178425326, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | tert-Butyl hydroperoxide | HCID 6410 | — |
| 반응물 | Acetylacetonate | HCID 5460482 | — |
| 반응물 | HCID 178425333 | HCID 178425333 | — |
| 용매 | Chlorobenzene | HCID 7964 | — |
| 생성물 | HCID 178425326 | HCID 178425326 | 55% |
반응 단계
To 26.5 g (0.08 mol) of α-hydroxy-(2,4,6-trimethylbenzyl)-phenylethoxy phosphine oxide and 1 g (38 mmol) of vanadyl(IV) bis-acetylacetonate in 110 g of chlorobenzene there were added 28 g (0.22 mol) of 70 wt % strength aqueous tert-butylhydroperoxide and the mixture was stirred for a period of 20 h. The product was isolated by distillation. Yield: 55%, bp 180° C. (0.1 mbar).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05504236 |
| 출처 데이터셋 | uspto-grants-1996_04 |
| ORD ID | ord-f773752ed09d44b99d57bc4e1a016adb |
| 출처 메모 | uspto-grants-1996_04 |