HCID 53662264, compound → 5-(2-Chlorobenzyl)-4-methoxymethyl-beta-carboline-3-carbaldehyde-oxime

HRID 1720332Notes

Reaction equation

HRID 1720332 reaction equation
C(O[C:4]([C:6]1[N:7]=[CH:8][C:9]2[NH:10][C:11]3[C:16]([C:17]=2[C:18]=1[CH2:19][O:20][CH3:21])=[C:15]([CH2:22][C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][C:24]=1[Cl:29])[CH:14]=[CH:13][CH:12]=3)=O)C.ClC1C=CC(CC2C=CC=C3C=2C2C(COC)=C(C=[N:50][OH:51])N=CC=2N3)=CC=1>>[Cl:29][C:24]1[CH:25]=[CH:26][CH:27]=[CH:28][C:23]=1[CH2:22][C:15]1[CH:14]=[CH:13][CH:12]=[C:11]2[C:16]=1[C:17]1[C:18]([CH2:19][O:20][CH3:21])=[C:6]([CH:4]=[N:50][OH:51])[N:7]=[CH:8][C:9]=1[NH:10]2

Participants

3

Reactant 2

HCID 53662264HCID 53662264, compoundHCID 1363755785-(4-Chlorobenzyl)-4-methoxymethyl-beta-carboline-3-carbaldehyde-oxime

Product 1

HCID 1363755795-(2-Chlorobenzyl)-4-methoxymethyl-beta-carboline-3-carbaldehyde-oxime

Procedure

The preparation takes place from 5-(2-chlorobenzyl)-4-methoxymethyl-β-carboline-3-carboxylic acid ethyl ester over alcohol and aldehyde, such as described for 5-(4-chlorobenzyl)-4- methoxymethyl-β-carboline-3- carbaldehyde-oxime, melting point 209°-212° C.

Sources & evidence

ORD record
ord-1d3bfa4d33de4b6081a8e933bc8f4432
Source dataset
uspto-grants-1996_04
Patent number
US05506234

Reaction notes

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