Sesamol → HCID 57137063, compound

HRID 1720524Notes

Reaction equation

HRID 1720524 reaction equation
[C:1]([O:5][C:6]([N:8]1[CH2:12][CH2:11][CH2:10][C@H:9]1[CH:13]1[O:15][CH2:14]1)=[O:7])([CH3:4])([CH3:3])[CH3:2].[CH2:16]1[O:24][C:23]2[CH:22]=[CH:21][C:20]([OH:25])=[CH:19][C:18]=2[O:17]1>>[C:1]([O:5][C:6]([N:8]1[CH2:12][CH2:11][CH2:10][C@H:9]1[CH:13]([OH:15])[CH2:14][O:25][C:20]1[CH:21]=[CH:22][C:23]2[O:24][CH2:16][O:17][C:18]=2[CH:19]=1)=[O:7])([CH3:2])([CH3:3])[CH3:4]

Participants

3

Reactant 2

HCID 68289SesamolHCID 15297813tert-butyl (2S)-2-(oxiran-2-yl)pyrrolidine-1-carboxylate

Product 1

HCID 57137063HCID 57137063, compoundYield 73.1%

Procedure

By the same procedure as in Example 26-B), while using (2S)1-(tert-butoxycarbonyl)-2-(1,2-epoxyethyl)Pyrrolidine (2.00 g) and (3,4-methylenedioxy)phenol (2.72 g), there was obtained 2.41 g of the title compound.

Sources & evidence

ORD record
ord-421fbd0c561e4ba99bc9fac97e7fcc44
Source dataset
uspto-grants-1996_04
Patent number
US05506256

Reaction notes

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