HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethylene Glycol → 2-(2-Bromophenyl)-1,3-dioxolane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethylene Glycol | HCID 174 | — |
| Reactant | Water | HCID 962 | — |
| Reactant | Toluene | HCID 1140 | — |
| Reactant | p-Toluenesulfonic acid | HCID 6101 | — |
| Reactant | 2-Bromobenzaldehyde | HCID 81129 | — |
| Product | 2-(2-Bromophenyl)-1,3-dioxolane | HCID 553534 | — |
Reaction Steps
A 12 L 3-necked flask fitted with an overhead stirrer was charged with 2-bromobenzaldehyde (800 g, 4.324 moles), ethylene glycol (402.6 g, 6.485 moles), p-toluenesulfonic acid. H2O (3.95 g, 0.021 moles) and toluene (3.785 kg, 41.074 moles).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05512690 |
| Source dataset | uspto-grants-1996_04 |
| ORD ID | ord-849b18a715ab4dc499683edd6c39ad88 |
| Source note | uspto-grants-1996_04 |