Ethyl bromoacetate → HCID 21798256, compound

HRID 1721926Notes

Reaction equation

[CH2:1]([C:4]1[C:9]([OH:10])=[C:8]([Cl:11])[C:7]([Cl:12])=[C:6]([C:13]([C:15]2[N:19]([CH3:20])[N:18]=[CH:17][CH:16]=2)=[O:14])[CH:5]=1)[CH:2]=[CH2:3].Br[CH2:22][C:23]([O:25][CH2:26][CH3:27])=[O:24]>>[CH2:1]([C:4]1[C:9]([O:10][CH2:22][C:23]([O:25][CH2:26][CH3:27])=[O:24])=[C:8]([Cl:11])[C:7]([Cl:12])=[C:6]([C:13]([C:15]2[N:19]([CH3:20])[N:18]=[CH:17][CH:16]=2)=[O:14])[CH:5]=1)[CH:2]=[CH2:3]

Participants

Reactant 2

HCID 7748Ethyl bromoacetate

HCID 14719819HCID 14719819, compound

Product 1

HCID 21798256HCID 21798256, compoundYield 99.8%

Procedure

1.13 g of 6-allyl-2,3-dichloro-4-(1-methyl-5-pyrazolylcarbonyl)phenol and 0.67 g of ethyl bromoacetate are treated in the same manner as described in Example 1 to give 1.44 g of ethyl [6-allyl-2,3-dichloro-4-(1-methyl-5-pyrazolylcarbonyl)phenoxy]acetate. IRνmaxliquid (cm-1): 1755, 1735, 1665, 1640, 1585, 1550.

Sources & evidence

ORD record: ord-67054f4fe0d64e4183e768ec033e631a
Source dataset: uspto-grants-1989_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04853404

Reaction notes

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