Diethyl Ether → HCID 20030160, compound

HRID 1721930Notes

Reaction equation

HRID 1721930 reaction equation
[CH2:1]([C:4]1[C:9]([O:10][CH2:11][C:12]([O:14]CC)=[O:13])=[C:8]([Cl:17])[C:7]([Cl:18])=[C:6]([C:19]([C:21]2[N:25]([CH3:26])[N:24]=[CH:23][CH:22]=2)=[O:20])[CH:5]=1)[CH:2]=[CH2:3].CCOCC>CCCCCC>[CH2:1]([C:4]1[C:9]([O:10][CH2:11][C:12]([OH:14])=[O:13])=[C:8]([Cl:17])[C:7]([Cl:18])=[C:6]([C:19]([C:21]2[N:25]([CH3:26])[N:24]=[CH:23][CH:22]=2)=[O:20])[CH:5]=1)[CH:2]=[CH2:3]

Participants

4

Reactant 2

HCID 3283Diethyl EtherHCID 21798256HCID 21798256, compound

Product 1

HCID 20030160HCID 20030160, compoundYield 88.9%

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

1.44 g of ethyl [6-allyl-2,3-dichloro-4-(1-methyl-5-pyrazolylcarbonyl)phenoxy]acetate are treated in the same manner as described in Example 18 except that a mixture of ether and hexane is used as the crystallization solvent. 1.19 g of [6-allyl-2,3-dichloro-4-(1-methyl-5-pyrazolylcarbonyl)phenoxy]acetic acid are obtained as crystals.

Sources & evidence

ORD record
ord-e730c753ef554ab58c281963aa375e11
Source dataset
uspto-grants-1989_08
Patent number
US04853404

Reaction notes

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